Efnisyfirlit

• Brief Contents
• Contents
• Applications
• Preface
• About the Authors
• Unit I: Introduction to the Study of Modern Chemistry
  • Chapter 1: The Atom in Modern Chemistry
    • 1.1 The Nature of Modern Chemistry
    • 1.2 Elements: The Building Blocks of Matter
    • 1.3 Indirect Evidence for the Existence of Atoms: Laws of Chemical Combination
    • 1.4 The Physical Structure of Atoms
    • 1.5 Mass Spectrometry, Isotopes, and the Measurement of Relative Mass
    • 1.6 The Mole: Counting Molecules by Weighing
  • Chapter 2: Chemical Formulas, Equations, and Reaction Yields
    • 2.1 Empirical and Molecular Formulas
    • 2.2 Chemical Formula and Percentage Composition
    • 2.3 Writing Balanced Chemical Equations
    • 2.4 Mass Relationships in Chemical Reactions
    • 2.5 Limiting Reactant and Percentage Yield
• Unit II: Chemical Bonding and Molecular Structure
  • Chapter 3: Atomic Shells and Classical Models of Chemical Bonding
    • 3.1 Representations of Molecules
    • 3.2 The Periodic Table
    • 3.3 Forces and Potential Energy in Atoms
    • 3.4 Ionization Energies, the Shell Model of the Atom, and Shielding
    • 3.5 Electron Affinity
    • 3.6 Electronegativity: The Tendency of Atoms to Attract Electrons in Molecules
    • 3.7 Forces and Potential Energy in Molecules: Formation of Chemical Bonds
    • 3.8 Ionic Bonding
    • 3.9 Covalent and Polar Covalent Bonding
    • 3.10 Electron Pair Bonds and Lewis Diagrams for Molecules
    • 3.11 The Shapes of Molecules: Valence Shell Electron-Pair Repulsion Theory
    • 3.12 Oxidation Numbers
    • 3.13 Inorganic Nomenclature
  • Chapter 4: Introduction to Quantum Mechanics
    • 4.1 Preliminaries: Wave Motion and Light
    • 4.2 Evidence for Energy Quantization in Atoms
    • 4.3 The Bohr Model: Predicting Discrete Energy Levels in Atoms
    • 4.4 Evidence for Wave-Particle Duality
    • 4.5 The Schrodinger Equation
    • 4.6 Quantum Mechanics of Particle-in-a-Box Models
    • 4.7 A Deeper Look: Wave Functions for Particles in Two- and Three-Dimensional Boxes
  • Chapter 5: Quantum Mechanics and Atomic Structure
    • 5.1 The Hydrogen Atom
    • 5.2 Shell Model for Many-Electron Atoms
    • 5.3 Aufbau Principle and Electron Configurations
    • 5.4 Shells and the Periodic Table: Photoelectron Spectroscopy
    • 5.5 Periodic Properties and Electronic Structure
  • Chapter 6: Quantum Mechanics and Molecular Structure
    • 6.1 Quantum Picture of the Chemical Bond
    • 6.2 Exact Molecular Orbitals for the Simplest Molecule: H+2
    • 6.3 Molecular Orbital Theory and the Linear Combination of Atomic Orbitals Approximation for H+2
    • 6.4 Homonuclear Diatomic Molecules: First-Period Atoms
    • 6.5 Homonuclear Diatomic Molecules: Second-Period Atoms
    • 6.6 Heteronuclear Diatomic Molecules
    • 6.7 Summary Comments for the LCAO Method and Diatomic Molecules
    • 6.8 Valence Bond Theory and the Electron Pair Bond
    • 6.9 Orbital Hybridization for Polyatomic Molecules
    • 6.10 Predicting Molecular Structures and Shapes
    • 6.11 Using the LCAO and Valence Bond Methods Together
    • 6.12 Summary and Comparison of the LCAO and Valence Bond Methods
    • 6.13 A Deeper Look: Properties of the Exact Molecular Orbitals for H+2
  • Chapter 7: Bonding in Organic Molecules
    • 7.1 Petroleum Refining and the Hydrocarbons
    • 7.2 The Alkanes
    • 7.3 The Alkenes and Alkynes
    • 7.4 Aromatic Hydrocarbons
    • 7.5 Fullerenes
    • 7.6 Functional Groups and Organic Reactions
    • 7.7 Pesticides and Pharmaceuticals
  • Chapter 8: Bonding in Transition Metal Compounds and Coordination Complexes
    • 8.1 Chemistry of the Transition Metals
    • 8.2 Introduction to Coordination Chemistry
    • 8.3 Structures of Coordination Complexes
    • 8.4 Crystal Field Theory: Optical and Magnetic Properties
    • 8.5 Optical Properties and the Spectrochemical Series
    • 8.6 Bonding in Coordination Complexes
• Unit III: Kinetic Molecular Description of the States of Matter
  • Chapter 9: The Gaseous State
    • 9.1 The Chemistry of Gases
    • 9.2 Pressure and Temperature of Gases
    • 9.3 The Ideal Gas Law
    • 9.4 Mixtures of Gases
    • 9.5 The Kinetic Theory of Gases
    • 9.6 Real Gases: Intermolecular Forces
    • 9.7 A Deeper Look: Molecular Collisions and Rate Processes
  • Chapter 10: Solids, Liquids, and Phase Transitions
    • 10.1 Bulk Properties of Gases, Liquids, and Solids: Molecular Interpretation
    • 10.2 Intermolecular Forces: Origins in Molecular Structure
    • 10.3 Intermolecular Forces in Liquids
    • 10.4 Phase Equilibrium
    • 10.5 Phase Transitions
    • 10.6 Phase Diagrams
  • Chapter 11: Solutions
    • 11.1 Composition of Solutions
    • 11.2 Nature of Dissolved Species
    • 11.3 Reaction Stoichiometry in Solutions: Acid-Base Titrations
    • 11.4 Reaction Stoichiometry in Solutions: Oxidation-Reduction Titrations
    • 11.5 Phase Equilibrium in Solutions: Nonvolatile Solutes
    • 11.6 Phase Equilibrium in Solutions: Volatile Solutes
    • 11.7 Colloidal Suspensions
• Unit IV: Equilibrium in Chemical Reactions
  • Chapter 12: Thermodynamic Processes and Thermochemistry
    • 12.1 Systems, States, and Processes
    • 12.2 The First Law of Thermodynamics: Internal Energy, Work, and Heat
    • 12.3 Heat Capacity, Calorimetry, and Enthalpy
    • 12.4 The First Law and Ideal Gas Processes
    • 12.5 Molecular Contributions to Internal Energy and Heat Capacity
    • 12.6 Thermochemistry
    • 12.7 Reversible Processes in Ideal Gases
    • 12.8 A Deeper Look: Distribution of Energy among Molecules
  • Chapter 13: Spontaneous Processes and Thermodynamic Equilibrium
    • 13.1 The Nature of Spontaneous Processes
    • 13.2 Entropy and Spontaneity: A Molecular Statistical Interpretation
    • 13.3 Entropy and Heat: Macroscopic Basis of the Second Law of Thermodynamics
    • 13.4 Entropy Changes in Reversible Processes
    • 13.5 Entropy Changes and Spontaneity
    • 13.6 The Third Law of Thermodynamics
    • 13.7 The Gibbs Free Energy
    • 13.8 A Deeper Look: Carnot Cycles, Efficiency, and Entropy
  • Chapter 14: Chemical Equilibrium
    • 14.1 The Nature of Chemical Equilibrium
    • 14.2 The Empirical Law of Mass Action
    • 14.3 Thermodynamic Description of the Equilibrium State
    • 14.4 The Law of Mass Action for Related and Simultaneous Equilibria
    • 14.5 Equilibrium Calculations for Gas-Phase and Heterogeneous Reactions
    • 14.6 The Direction of Change in Chemical Reactions: Empirical Description
    • 14.7 The Direction of Change in Chemical Reactions: Thermodynamic Explanation
    • 14.8 Distribution of a Single Species between Immiscible Phases: Extraction and Separation Processes
  • Chapter 15: Acid-Base Equilibria
    • 15.1 Classifications of Acids and Bases
    • 15.2 Properties of Acids and Bases in Aqueous Solutions: The Bronsted-Lowry Scheme
    • 15.3 Acid and Base Strength
    • 15.4 Equilibria Involving Weak Acids and Bases
    • 15.5 Buffer Solutions
    • 15.6 Acid-Base Titration Curves
    • 15.7 Polyprotic Acids
    • 15.8 Organic Acids and Bases: Structure and Reactivity
    • 15.9 A Deeper Look: Exact Treatment of Acid-Base Equilibria
  • Chapter 16: Solubility and Precipitation Equilibria
    • 16.1 The Nature of Solubility Equilibria
    • 16.2 Ionic Equilibria between Solids and Solutions
    • 16.3 Precipitation and the Solubility Product
    • 16.4 The Effects of pH on Solubility
    • 16.5 Complex Ions and Solubility
    • 16.6 A Deeper Look: Selective Precipitation of Ions
  • Chapter 17: Electrochemistry
    • 17.1 Electrochemical Cells
    • 17.2 Cell Potentials and the Gibbs Free Energy
    • 17.3 Concentration Effects and the Nernst Equation
    • 17.4 Molecular Electrochemistry
    • 17.5 Batteries and Fuel Cells
    • 17.6 Corrosion and Corrosion Prevention
    • 17.7 Electrometallurgy
    • 17.8 A Deeper Look: Electrolysis of Water and Aqueous Solutions
• Unit V: Rates of Chemical and Physical Processes
  • Chapter 18: Chemical Kinetics
    • 18.1 Rates of Chemical Reactions
    • 18.2 Rate Laws
    • 18.3 Reaction Mechanisms
    • 18.4 Reaction Mechanisms and Rate
    • 18.5 Effect of Temperature on Reaction Rates
    • 18.6 Molecular Theories of Elementary Reactions
    • 18.7 Reactions in Solution
    • 18.8 Catalysis
  • Chapter 19: Nuclear Chemistry
    • 19.1 Mass-Energy Relationships in Nuclei
    • 19.2 Nuclear Decay Processes
    • 19.3 Kinetics of Radioactive Decay
    • 19.4 Radiation in Biology and Medicine
    • 19.5 Nuclear Fission
    • 19.6 Nuclear Fusion and Nucleosynthesis
  • Chapter 20: Molecular Spectroscopy and Photochemistry
    • 20.1 Introduction to Molecular Spectroscopy
    • 20.2 Experimental Methods in Molecular Spectroscopy
    • 20.3 Rotational and Vibrational Spectroscopy
    • 20.4 Nuclear Magnetic Resonance Spectroscopy
    • 20.5 Electronic Spectroscopy and Excited State Relaxation Processes
    • 20.6 Introduction to Atmospheric Chemistry
    • 20.7 Photosynthesis
    • 20.8 A Deeper Look: Lasers
• Unit VI: Materials
  • Chapter 21: Structure and Bonding in Solids
    • 21.1 Crystal Symmetry and the Unit Cell
    • 21.2 Crystal Structure
    • 21.3 Cohesion in Solids
    • 21.4 Defects and Amorphous Solids
    • 21.5 A Deeper Look: Lattice Energies of Crystals
  • Chapter 22: Inorganic Materials
    • 22.1 Minerals: Naturally Occurring Inorganic Materials
    • 22.2 Properties of Ceramics
    • 22.3 Silicate Ceramics
    • 22.4 Nonsilicate Ceramics
    • 22.5 Electrical Conduction in Materials
    • 22.6 Band Theory of Conduction
    • 22.7 Semiconductors
    • 22.8 Pigments and Phosphors: Optical Displays
  • Chapter 23: Polymeric Materials and Soft Condensed Matter
    • 23.1 Polymerization Reactions for Synthetic Polymers
    • 23.2 Applications for Synthetic Polymers
    • 23.3 Liquid Crystals
    • 23.4 Natural Polymers
• Appendices
  • Appendix A: Scientific Notation and Experimental Error
  • Appendix B: SI Units, Unit Conversions, and Physics for General Chemistry
  • Appendix C: Mathematics for General Chemistry
  • Appendix D: Standard Chemical Thermodynamic Properties
  • Appendix E: Standard Reduction Potentials at 25 Degrees Celsius
  • Appendix F: Physical Properties of the Elements
  • Appendix G: Answers to Odd-Numbered Problems
• Index/Glossary

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